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Rh(2) (S-biTISP)(2)-Catalyzed Asymmetric Functionalization of Indoles and Pyrroles with Vinylcarbenoids

[Image: see text] Asymmetric functionalization of N-heterocycles by vinylcarbenoids in the presence of catalytic amounts of Rh(2) (S-biTISP)(2) has been successfully developed. This bridged dirhodium catalyst not only selectively enforces the reaction to occur at the vinylogous position of the carbe...

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Détails bibliographiques
Auteurs principaux: Lian, Yajing, Davies, Huw M. L.
Format: Artigo
Langue:Inglês
Publié: 2012
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3351204/
https://ncbi.nlm.nih.gov/pubmed/22452332
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol300632p
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