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Stereocontrol in a Combined Allylic Azide Rearrangement and Intramolecular Schmidt Reaction
Preequilibration of an interconverting set of isomeric allylic azides is coupled with an intramolecular Schmidt reaction to stereoselectively afford substituted lactams. The effect of substitution and a preliminary mechanistic study are reported. The synthetic potential of this method is demonstrate...
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| Hauptverfasser: | , , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3340293/ https://ncbi.nlm.nih.gov/pubmed/22490078 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja300369c |
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