Spectroscopic and Crystallographic Characterization of ‘Alternative Resting’ and ‘Resting Oxidized’ Enzyme Forms of Bilirubin Oxidase: Implications for Activity and Electrochemical Behavior of Multicopper Oxidases

While there is broad agreement on the catalytic mechanism of Multicopper Oxidases (MCOs), the geometric and electronic structures of the resting trinuclear Cu cluster have been variable, and their relevance to catalysis debated. Here, we present a spectroscopic characterization, complimented by crys...

Πλήρης περιγραφή

Αποθηκεύτηκε σε:
Λεπτομέρειες βιβλιογραφικής εγγραφής
Κύριοι συγγραφείς: Kjaergaard, Christian H., Durand, Fabien, Tasca, Federico, Qayyum, Munzarin F., Kaufmann, Brice, Gounel, Sébastien, Suraniti, Emmanuel, Hodgson, Keith O., Hedman, Britt, Mano, Nicolas, Solomon, Edward I.
Μορφή: Artigo
Γλώσσα:Inglês
Έκδοση: 2012
Θέματα:
Article
Διαθέσιμο Online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3339634/
https://ncbi.nlm.nih.gov/pubmed/22413777
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211872j
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