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Synthesis of α-Arylphosphonates Using Copper-Catalyzed α-Arylation and Deacylative α-Arylation of β-Ketophosphonates

Efficient methods for the direct arylation and deacylative arylation of β-ketophosphonates with iodoarenes in presence of a copper(I) or a copper(II) salt as the catalysts were developed. The corresponding α-arylphosphonates were obtained in high yields. A tentative mechanism for the deacylative ary...

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Autors principals: Rout, Laxmidhar, Regati, Sridhar, Zhao, Cong-Gui
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3324819/
https://ncbi.nlm.nih.gov/pubmed/22505878
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/adsc.201100605
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