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Organocatalyzed asymmetric Michael reaction of β-aryl-α-ketophosphonates and nitroalkenes
The first enantioselective Michael reaction of β-aryl-α-ketophosphonates and nitroalkenes has been brealized by using a new bifunctional Takemoto-type thiourea catalyst. The primary Michael adducts obtained were converted in situ to the corresponding amides through the aminolysis. High yields, excel...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2013
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3810965/ https://ncbi.nlm.nih.gov/pubmed/24187390 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2013.08.015 |
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