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Three-Component Glycolate Michael Reactions of Enolates, Silyl Glyoxylates, and α,β-Enones
Silyl glyoxylates react with enolates and enones to afford either glycolate aldol or Michael adducts. Product identity is controlled by the countercation associated with the enolate. Reformatsky nucleophiles in the presence of additional Zn(OTf)(2) result in aldol coupling (A), while lithium enolate...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3321131/ https://ncbi.nlm.nih.gov/pubmed/22394389 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo202679u |
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