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A Paradigm for Enzyme-Catalyzed Proton Transfer at Carbon: Triosephosphate Isomerase
Triosephosphate isomerase (TIM) catalyzes the stereospecific 1,2-proton shift at dihydroxyacetone phosphate (DHAP) to give (R)-glyceraldehyde 3-phosphate through a pair of isomeric enzyme-bound cis-enediolate phosphate intermediates. The chemical transformations that occur at the active site of TIM...
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| Hovedforfatter: | |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2012
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3319633/ https://ncbi.nlm.nih.gov/pubmed/22409228 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/bi300195b |
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