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Palladacyclic Imidazoline-Naphthalene Complexes: Synthesis and Catalytic Performance in Pd(II)-Catalyzed Enantioselective Reactions of Allylic Trichloroacetimidates

[Image: see text] A new family of air- and moisture-stable enantiopure C,N-palladacycles (PIN-acac complexes) were prepared in good overall yield in three steps from 2-iodo-1-naphthoic acid and enantiopure β-amino alcohols. Three of these PIN complexes were characterized by single-crystal X-ray anal...

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Autori principali: Cannon, Jeffrey S., Frederich, James H., Overman, Larry E.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2012
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3288570/
https://ncbi.nlm.nih.gov/pubmed/22288535
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo2025724
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