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A Peptide-Embedded Trifluoromethyl Ketone Catalyst for Enantioselective Epoxidation
[Image: see text] The development of peptide-based oxidation catalysts that use a transiently generated dioxirane as the chemically active species is reported. The active catalyst is a chiral trifluoromethyl ketone (Tfk) with a pendant carboxylic acid that can be readily incorporated into a peptide....
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| Autors principals: | , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2012
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3288446/ https://ncbi.nlm.nih.gov/pubmed/22315978 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol3000712 |
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