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Exploratory Experiments on the Chemistry of the “Glyoxylate Scenario”: Formation of Ketosugars from Dihydroxyfumarate

[Image: see text] In the context of a “glyoxylate scenario” of primordial metabolism,(1) the reactions of dihydroxyfumarate (DHF) with reactive small molecule aldehydes (e.g., glyoxylate, formaldehyde, glycolaldehyde, and glyceraldehyde) in water were investigated and shown to form dihydroxyacetone,...

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Main Authors: Sagi, Vasudeva Naidu, Punna, Venkateshwarlu, Hu, Fang, Meher, Geeta, Krishnamurthy, Ramanarayanan
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2012
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3284196/
https://ncbi.nlm.nih.gov/pubmed/22280414
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja211383c
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