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Protonation of Homoenolate Equivalents Generated by N-Heterocyclic Carbenes
Homoenolate equivalents are generated by Lewis basic N-heterocyclic carbene catalysts and then protonated to generate efficiently saturated esters from unsaturated aldehydes. This reactivity is extended to the generation of β-acylvinyl anions from alkynyl aldehydes. The asymmetric protonation of a h...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2008
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3279924/ https://ncbi.nlm.nih.gov/pubmed/22347730 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1055/s-2008-1072516 |
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