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N-Heterocyclic Carbene-Catalyzed Oxidations

N-Heterocyclic carbenes catalyze the oxidation of allylic and benzylic alcohols as well as saturated aldehydes to esters with manganese(IV) oxide in excellent yields. A variety of esters can be synthesized, including protected carboxylates. The oxidation proceeds under mild conditions, with low load...

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Detalhes bibliográficos
Main Authors: Maki, Brooks E., Chan, Audrey, Phillips, Eric M., Scheidt, Karl A.
Formato: Artigo
Idioma:Inglês
Publicado em: 2009
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2704494/
https://ncbi.nlm.nih.gov/pubmed/20161230
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2008.10.033
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