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The Impact of Solvent Polarity on N-Heterocyclic Carbene-Catalyzed β-Protonations of Homoenolate Equivalents
[Image: see text] N-Heterocyclic carbenes have been demonstrated to react through divergent pathways under the same conditions. Experimental and computational evidence demonstrates that the ability to favor generation of homoenolate equivalents from α,β-unsaturated aldehydes versus the oxidation of...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2733935/ https://ncbi.nlm.nih.gov/pubmed/19645427 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol901545m |
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