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Mechanical Force Can Fine-Tune Redox Potentials of Disulfide Bonds

Mechanical force applied along a disulfide bond alters its rate of reduction. We here aimed at quantifying the direct effect of force onto the chemical reactivity of a sulfur-sulfur bond in contrast to indirect, e.g., steric or mechanistic, influences. To this end, we evaluated the dependency of a d...

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Detalhes bibliográficos
Main Authors: Baldus, Ilona B., Gräter, Frauke
Formato: Artigo
Idioma:Inglês
Publicado em: The Biophysical Society 2012
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3274805/
https://ncbi.nlm.nih.gov/pubmed/22325286
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.bpj.2011.12.039
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