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Charge Photoinjection in Intercalated and Covalently Bound [Re(CO)(3)(dppz)(py)](+)-DNA Constructs Monitored by Time Resolved Visible and Infrared Spectroscopy

The complex [Re(CO)(3)(dppz)(py′-OR)](+) (dppz = dipyrido[3,2-a:2′,3′-c]phenazine; py′-OR = 4-functionalized pyridine) offers IR sensitivity and can oxidize DNA directly from the excited state, making it a promising probe for the study of DNA-mediated charge transport (CT). The behavior of several c...

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Detalhes bibliográficos
Main Authors: Olmon, Eric D., Sontz, Pamela A., Blanco-Rodríguez, Ana María, Towrie, Michael, Clark, Ian P., Vlček, Antonín, Barton, Jacqueline K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3227519/
https://ncbi.nlm.nih.gov/pubmed/21827149
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja205568r
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