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Synthesis enables a structural revision of the Mycobacterium tuberculosis-produced diterpene, edaxadiene()
A stereodivergent synthesis of the [3.3.1] bicyclic core of edaxadiene was completed utilizing a key intramolecular oxidative ketone allylation. Significant discrepancies between the spectroscopic data obtained for the synthetic construct and the natural isolate raised questions about the structural...
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| Hauptverfasser: | , , |
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| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2010
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3221386/ https://ncbi.nlm.nih.gov/pubmed/22114734 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/C0SC00284D |
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