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Synthesis of (±)-Nosyberkol (Isotuberculosinol, Revised Structure of Edaxadiene) and (±)-Tuberculosinol

[Image: see text] Me(2)AlCl-catalyzed Diels–Alder reaction of N-tigloyloxazolidinone with 6,6-dimethyl-1-vinylcyclohexene selectively provided the exo adduct, which was converted to nosyberkol (isotuberculosinol) and tuberculosinol. The spectral data for nosyberkol are identical to those reported fo...

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Bibliografiska uppgifter
Huvudupphovsmän: Maugel, Nathan, Mann, Francis M., Hillwig, Matthew L., Peters, Reuben J., Snider, Barry B.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2010
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Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC2880386/
https://ncbi.nlm.nih.gov/pubmed/20462237
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100832h
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