X-ray Absorption Spectroscopy and Reactivity of Thiolate-Ligated Fe(III)-OOR Complexes

The reaction of a series of thiolate-ligated iron(II) complexes [Fe(II)([15]aneN(4))(SC(6)H(5))]BF(4) (1), [Fe(II)([15]aneN(4))(SC(6)H(4)-p-Cl)]BF(4) (2), and [Fe(II)([15]aneN(4))(SC(6)H(4)-p-NO(2))]BF(4) (3) with alkylhydroperoxides at low temperature (−78 °C or −40 °C) leads to the metastable alky...

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Main Authors: Stasser, Jay, Namuswe, Frances, Kasper, Gary D., Jiang, Yunbo, Krest, Courtney M., Green, Michael T., Penner-Hahn, James, Goldberg, David P.
Format: Artigo
Jezik:Inglês
Izdano: 2010
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Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC3221327/
https://ncbi.nlm.nih.gov/pubmed/20839847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic100670k
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