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Rational Tuning of the Thiolate Donor in Model Complexes of Superoxide Reductase: Direct Evidence for a Trans Influence in Fe(III)-OOR Complexes

Iron peroxide species have been identified as important intermediates in a number of non-heme iron as well as heme-containing enzymes, yet there are only a few examples of such species either synthetic or biological that have been well characterized. We describe the synthesis and structural characte...

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Main Authors: Namuswe, Frances, Kasper, Gary D., Narducci Sarjeant, Amy A., Hayashi, Takahiro, Krest, Courtney M., Green, Michael T., Moënne-Loccoz, Pierre, Goldberg, David P.
格式: Artigo
語言:Inglês
出版: 2008
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC2744891/
https://ncbi.nlm.nih.gov/pubmed/18837497
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8031828
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