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N(2) Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex

The most common catalyst in the Haber-Bosch process for the hydrogenation of dinitrogen (N(2)) to ammonia is an iron surface promoted with K(+), but soluble iron complexes have neither reduced the N-N bond of N(2) to nitride nor produced large amounts of NH(3) from N(2). We report a molecular iron c...

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Detalhes bibliográficos
Main Authors: Rodriguez, Meghan M., Bill, Eckhard, Brennessel, William W., Holland, Patrick L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3218428/
https://ncbi.nlm.nih.gov/pubmed/22076372
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1211906
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