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First total synthesis of (+)-Vedelianin, a potent antiproliferative agent
The total synthesis of (+)-vedelianin has been accomplished in 18 steps from vanillin. Preparation of a key intermediate in nonracemic form through a Shi epoxidation has allowed determination of the absolute stereochemistry of the natural product as the (2S, 3R, 4aR, 9aR)-isomer.
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| Main Authors: | , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3204860/ https://ncbi.nlm.nih.gov/pubmed/22053119 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2011.01.137 |
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