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Chlorotrimethylsilane activation of acylcyanamides for the synthesis of mono-N-acylguanidines

[Image: see text] A simple and efficient one-pot method for the synthesis of mono-protected guanidines is presented. Treatment of an acylcyanamide with chlorotrimethylsilane generates a reactive N-silylcarbodiimide capable of guanylating a variety of amines. Typically the reaction is complete in 15...

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Autori principali: Looper, Ryan E., Haussener, Travis J., Mack, James B. C.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3189699/
https://ncbi.nlm.nih.gov/pubmed/21732649
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201264j
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