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On Orthogonal and Selective Activation of Glycosyl Thioimidates and Thioglycosides: Application to Oligosaccharide Assembly
[Image: see text] Discrimination amongst S-thiazolinyl (STaz), S-benzoxazolyl (SBox), and S-ethyl anomeric leaving group was achieved by fine-tuning of the activation conditions. Preferential glycosidation of a certain leaving group is neither determined by the strength of activating reagents nor th...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2011
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3170487/ https://ncbi.nlm.nih.gov/pubmed/21797272 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201117s |
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