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Unexpected Orthogonality of S-Benzoxazolyl and S-Thiazolinyl Glycosides: Application to Expeditious Oligosaccharide Assembly
[Image: see text] Thorough mechanistic studies of the alkylation pathway for the activation of glycosyl thioimidates have led to the development of the “thioimidate-only orthogonal strategy”. Discrimination amongst S-thiazolinyl (STaz) and S-benzoxazolyl (SBox) anomeric leaving group was achieved by...
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| Main Authors: | , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2642804/ https://ncbi.nlm.nih.gov/pubmed/19161321 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802740b |
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