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On Orthogonal and Selective Activation of Glycosyl Thioimidates and Thioglycosides: Application to Oligosaccharide Assembly

[Image: see text] Discrimination amongst S-thiazolinyl (STaz), S-benzoxazolyl (SBox), and S-ethyl anomeric leaving group was achieved by fine-tuning of the activation conditions. Preferential glycosidation of a certain leaving group is neither determined by the strength of activating reagents nor th...

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Detalhes bibliográficos
Main Authors: Kaeothip, Sophon, Demchenko, Alexei V.
Formato: Artigo
Idioma:Inglês
Publicado em: 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3170487/
https://ncbi.nlm.nih.gov/pubmed/21797272
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201117s
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