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Long-range diastereoselectivity in Ugi reactions of 2-substituted dihydrobenzoxazepines

The Ugi reaction of 2-substituted dihydrobenzoxazepines was found to proceed with unexpectedly good diastereoselectivitiy (diastereoisomeric ratios up to 9:1), despite the large distance between the pre-existing stereogenic centre and the newly generated one. This result represents the first good 1,...

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Hlavní autoři: Banfi, Luca, Basso, Andrea, Cerulli, Valentina, Rocca, Valeria, Riva, Renata
Médium: Artigo
Jazyk:Inglês
Vydáno: Beilstein-Institut 2011
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC3170203/
https://ncbi.nlm.nih.gov/pubmed/21915196
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.109
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