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Two Metals Are Better Than One in the Gold Catalyzed Oxidative Heteroarylation of Alkenes
We present a detailed study of the mechanism for oxidative heteroarylation, based on DFT calculations and experimental observations. We propose binuclear Au(II)-Au(II) complexes to be key intermediates in the mechanism for gold catalyzed oxidative heteroarylation. The reaction is thought to proceed...
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| Autori principali: | , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3168709/ https://ncbi.nlm.nih.gov/pubmed/21861448 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2012627 |
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