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Total Synthesis of (+)-SCH 351448
[Image: see text] A convergent synthesis of (+)-SCH 351448 (1), a monosodium salt of a C(2)-symmetric macrodiolide, is described. Our approach is based on a [4+2] annulation with a chiral allyl silane (anti-5c) to assemble the pyran subunits. Homodimerization was carried out in a stepwise fashion; i...
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| Autori principali: | , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164292/ https://ncbi.nlm.nih.gov/pubmed/21834568 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol201863b |
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