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Vinylogous Aldol Products From Chiral Crotylsilanes Obtained By Enantioselective Rh(II) and Cu(I) Carbenoid Si-H Insertion
[Image: see text] Enantioenriched homoallylic ethers linked to an α,β-unsaturated ester (syn-vinylogous aldol products) were directly accessed by Lewis acid catalyzed crotylation utilizing chiral silane 2. The reagents were prepared by enantioselective Si-H insertion to an α-diazovinylacetates using...
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| Glavni autori: | , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2010
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3164278/ https://ncbi.nlm.nih.gov/pubmed/20387893 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol100604m |
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