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Alkynoate Synthesis via Vinylogous Reactivity of Rh(II) Carbenoids
A new rhodium carbenoid approach to access alkynoates has been developed. This transformation combines the addition of enol ethers at the vinylogous position of β-siloxy-substituted vinyldiazo derivatives and an unprecedented siloxy group migration to yield the products as single diastereomers.
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2012
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3580044/ https://ncbi.nlm.nih.gov/pubmed/22807172 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201204047 |
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