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Combined C—H Functionalization/Cope Rearrangement with Vinyl Ethers as a Surrogate for the Vinylogous Mukaiyama Aldol Reaction
Vinyl ethers selectively undergo the combined C—H functionalization/Cope rearrangement reaction (CHCR) via an s-cis/boat transition. With chiral dirhodium catalysts, products are generated in a highly diastereoselective and enantioselective fashion. This reaction can be considered as a surrogate to...
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| Auteurs principaux: | , |
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| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
2011
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3314713/ https://ncbi.nlm.nih.gov/pubmed/21739977 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2051155 |
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