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Assignment and Stereocontrol of Hibarimicin Atropoisomers
[Image: see text] A stereochemical feature of the hibarimicins is a central biaryl (HMP-Y6) or aryl-quinone (hibarimicinone) incorporated as a single atropodiastereomer. Herein, a chiral resolution and deracemization process to access optically enriched biaryls aR-3 and aS-3 is described. From these...
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| Glavni autori: | , , , , , , |
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| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2011
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| Teme: | |
| Online pristup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3163008/ https://ncbi.nlm.nih.gov/pubmed/21812391 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2017005 |
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