A carregar...
Steric Crowding Makes Challenging C(sp3)–F Reductive Eliminations Feasible
A high-yielding fluorination of (triphos)Pt-R(+) has been achieved using an array of F(+) sources, with XeF(2) yielding R–F in minutes. The C–F coupling proved to be a stereoretentive process that proceeds via a concerted reductive elimination from a putative dicationic Pt(IV) center. The larger the...
Na minha lista:
| Main Authors: | , , |
|---|---|
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3159157/ https://ncbi.nlm.nih.gov/pubmed/21869853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om200515f |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|