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Steric Crowding Makes Challenging C(sp3)–F Reductive Eliminations Feasible
A high-yielding fluorination of (triphos)Pt-R(+) has been achieved using an array of F(+) sources, with XeF(2) yielding R–F in minutes. The C–F coupling proved to be a stereoretentive process that proceeds via a concerted reductive elimination from a putative dicationic Pt(IV) center. The larger the...
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| Main Authors: | , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3159157/ https://ncbi.nlm.nih.gov/pubmed/21869853 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om200515f |
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