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Biocatalytic Organic Synthesis of Optically Pure (S)-Scoulerine and Berbine and Benzylisoquinoline Alkaloids
[Image: see text] A chemoenzymatic approach for the asymmetric total synthesis of the title compounds is described that employs an enantioselective oxidative C–C bond formation catalyzed by berberine bridge enzyme (BBE) in the asymmetric key step. This unique reaction yielded enantiomerically pure (...
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| Autori principali: | , , , , , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
American Chemical Society
2011
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| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3155283/ https://ncbi.nlm.nih.gov/pubmed/21739961 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jo201056f |
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