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The Use of Symmetry in Enantioselective Synthesis: Four Pairs of Chrysene Enantiomers Prepared From 19-Nortestosterone

Expansion of the D-ring of 19-norsteroids with incorporation of the steroid C-18 methyl group into a newly formed six-membered ring provides easy access to the chrysene ring system. By taking advantage of the symmetry of the chrysene ring system and avoiding meso chrysene intermediates, four optical...

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Autori principali: Stastna, Eva, Rath, Nigam P., Covey, Douglas F.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3154374/
https://ncbi.nlm.nih.gov/pubmed/21541379
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c1ob05385j
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