Acetoxy Meldrum’s Acid: A Versatile Acyl Anion Equivalent in the Pd-Catalyzed Asymmetric Allylic Alkylation

[Image: see text] Acetoxy Meldrum’s acid can serve as a versatile acyl anion equivalent in the Pd-catalyzed asymmetric allylic alkylation. The reaction of this nucleophile with various meso and racemic electrophiles afforded alkylated products in high yields and enantiopurities. These enantioenriche...

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Autori principali: Trost, Barry M., Osipov, Maksim, Kaib, Philip S. J., Sorum, Mark T.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Article
Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3144701/
https://ncbi.nlm.nih.gov/pubmed/21615099
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol2011242
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