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High chemoselectivity in the phenol synthesis

Efforts to trap early intermediates of the gold-catalyzed phenol synthesis failed. Neither inter- nor intramolecularly offered vinyl groups, ketones or alcohols were able to intercept the gold carbenoid species. This indicates that the competing steps of the gold-catalyzed phenol synthesis are much...

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Detalhes bibliográficos
Main Authors: Rudolph, Matthias, McCreery, Melissa Q, Frey, Wolfgang, Hashmi, A Stephen K
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3135103/
https://ncbi.nlm.nih.gov/pubmed/21804874
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.7.90
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