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Facile Access to Sterically Hindered Aryl Ketones via Carbonylative Cross-Coupling: Application to the Total Synthesis of Luteolin

A general and mild protocol for achieving the carbonylative cross-coupling of sterically-hindered, ortho-disubstituted aryl ketones is reported. The commercially available PEPPSI-IPr catalyst is shown to efficiently promote the carbonylative cross-coupling of hindered ortho-disubstituted aryl iodide...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: O’Keefe, B. Michael, Simmons, Nicholas, Martin, Stephen F.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2011
Schlagworte:
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3122923/
https://ncbi.nlm.nih.gov/pubmed/21712966
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.03.074
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