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Visible Light Photocatalysis of Radical Anion Hetero-Diels–Alder Cycloadditions
We have discovered a photocatalytic intramolecular hetero-Diels–Alder reaction of tethered bis(enones). This transformation involves the intermediacy of an enone radical anion and constitutes the formal coupling of an electron-deficient heterodiene with an electronically mismatched enone dienophile....
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| Autori principali: | , , , |
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| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
2011
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3110713/ https://ncbi.nlm.nih.gov/pubmed/21666769 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.02.066 |
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