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Visible Light Photocatalysis of Radical Anion Hetero-Diels–Alder Cycloadditions

We have discovered a photocatalytic intramolecular hetero-Diels–Alder reaction of tethered bis(enones). This transformation involves the intermediacy of an enone radical anion and constitutes the formal coupling of an electron-deficient heterodiene with an electronically mismatched enone dienophile....

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Sonraí Bibleagrafaíochta
Main Authors: Hurtley, Anna E., Cismesia, Megan A., Ischay, Michael A., Yoon, Tehshik P.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2011
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3110713/
https://ncbi.nlm.nih.gov/pubmed/21666769
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2011.02.066
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