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Radical Cation Diels–Alder Cycloadditions by Visible Light Photocatalysis

Ruthenium(II) polypyridyl complexes promote the efficient radical cation Diels–Alder cycloaddition of electron-rich dienophiles upon irradiation with visible light. These reactions enable facile [4+2] cycloadditions that would be electronically mismatched under thermal conditions. Key to the success...

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Autori principali: Lin, Shishi, Ischay, Michael A., Fry, Charles G., Yoon, Tehshik P.
Natura: Artigo
Lingua:Inglês
Pubblicazione: 2011
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC3227774/
https://ncbi.nlm.nih.gov/pubmed/22032252
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2093579
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