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Radical Cation Diels–Alder Cycloadditions by Visible Light Photocatalysis
Ruthenium(II) polypyridyl complexes promote the efficient radical cation Diels–Alder cycloaddition of electron-rich dienophiles upon irradiation with visible light. These reactions enable facile [4+2] cycloadditions that would be electronically mismatched under thermal conditions. Key to the success...
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| Main Authors: | , , , |
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| Format: | Artigo |
| Language: | Inglês |
| Published: |
2011
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| Subjects: | |
| Online Access: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3227774/ https://ncbi.nlm.nih.gov/pubmed/22032252 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja2093579 |
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