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Breaking the regioselectivity rule for acrylate insertion in the Mizoroki–Heck reaction

In modern methods for the preparation of small molecules and polymers, the insertion of substrate carbon–carbon double bonds into metal–carbon bonds is a fundamental step of paramount importance. This issue is illustrated by Mizoroki–Heck coupling as the most prominent example in organic synthesis a...

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Detalhes bibliográficos
Main Authors: Wucher, Philipp, Caporaso, Lucia, Roesle, Philipp, Ragone, Francesco, Cavallo, Luigi, Mecking, Stefan, Göttker-Schnetmann, Inigo
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3107328/
https://ncbi.nlm.nih.gov/pubmed/21562208
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1101497108
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