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Photodegradable branched polyethylenes from carbon monoxide copolymerization under benign conditions

Small amounts of in-chain keto groups render polyethylene (PE) photodegradable, a desirable feature in view of environmental plastics pollution. Free-radical copolymerization of CO and ethylene is challenging due to the formation of stable acyl radicals which hinders further chain growth. Here, we r...

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Detalhes bibliográficos
Publicado no:Nat Commun
Main Authors: Morgen, Tobias O., Baur, Maximilian, Göttker-Schnetmann, Inigo, Mecking, Stefan
Formato: Artigo
Idioma:Inglês
Publicado em: Nature Publishing Group UK 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC7378081/
https://ncbi.nlm.nih.gov/pubmed/32704075
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-020-17542-5
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