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Characterization of Tunable Radical Metal-Carbenes: Key Intermediates in Catalytic Cyclopropanation
A new class of radical metal-carbene complex has been characterized as having Fischer-like orbital interactions and adjacent π acceptor stabilization. Density Functional Theory (DFT) along with Natural Bond Orbital (NBO) analysis and Charge Decomposition Analysis (CDA) has given insight into the ele...
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| 主要な著者: | , , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2011
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3105361/ https://ncbi.nlm.nih.gov/pubmed/21643517 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/om2001348 |
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