Modelling the cis-oxo-labile binding site motif of non-heme iron oxygenases. Water exchange and remarkable oxidation reactivity of a novel non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand

The spectroscopic and chemical characterization of a new synthetic non-heme iron(IV)-oxo species [Fe(IV)(O)((Me,H)Pytacn)(S)](2+) (2, (Me,H)Pytacn = 1-(2′-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane, S = CH(3)CN or H(2)O) is described. 2 has been prepared by reaction of [Fe(II)(CF(3)SO(3))(2...

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Détails bibliographiques
Auteurs principaux: Company, Anna, Prat, Irene, Frisch, Jonathan R., Ballesté, Ruben Mas, Güell, Mireia, Juhász, Gergely, Ribas, Xavi, Münck, Eckard, Luis, Josep M., Que, Lawrence, Costas, Miquel
Format: Artigo
Langue:Inglês
Publié: 2011
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC3097279/
https://ncbi.nlm.nih.gov/pubmed/21268165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201002297
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