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A Palladium-Catalyzed Three-Component Cross-Coupling of Conjugated Dienes or Terminal Alkenes with Vinyl Triflates and Boronic Acids

A three-component coupling of vinyl triflates and boronic acids to alkenes catalyzed by palladium is reported. Using 1,3-dienes, selective 1,2-alkene difunctionalization is observed, whereas the use of terminal alkenes results in 1,1-alkene difunctionalization. The reaction outcome is attributed to...

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Autors principals: Liao, Longyan, Jana, Ranjan, Urkalan, Kaveri Balan, Sigman, Matthew S.
Format: Artigo
Idioma:Inglês
Publicat: 2011
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC3084658/
https://ncbi.nlm.nih.gov/pubmed/21449562
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja201358b
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