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Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative Conditions
[Image: see text] A palladium-catalyzed reductive cross coupling of 1,3-dienes with boronic esters is reported in which a π-allyl Pd-species is generated directly from a 1,3 diene via a Pd-catalyzed aerobic alcohol oxidation. Both the scope of the process and the origin of a highly selective 1,2-add...
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| Main Authors: | , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2911521/ https://ncbi.nlm.nih.gov/pubmed/20608751 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105010t |
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