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Palladium-Catalyzed Hydroarylation of 1,3-Dienes with Boronic Esters via Reductive Formation of π-Allyl Palladium Intermediates under Oxidative Conditions

[Image: see text] A palladium-catalyzed reductive cross coupling of 1,3-dienes with boronic esters is reported in which a π-allyl Pd-species is generated directly from a 1,3 diene via a Pd-catalyzed aerobic alcohol oxidation. Both the scope of the process and the origin of a highly selective 1,2-add...

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Detalhes bibliográficos
Main Authors: Liao, Longyan, Sigman, Matthew S.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2911521/
https://ncbi.nlm.nih.gov/pubmed/20608751
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja105010t
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