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Palladium Catalyzed Asymmetric Three Component Coupling of Boronic Esters, Indoles and Allylic Acetates

Boronic esters react with 2-lithiated indoles to form boronate intermediates. The boronate reacts with allylic acetates in the presence of (BINAP)Pd catalysts to allylate C3 concurrent with alkyl migration from B to C2 of the indole. Overall, the process is a three-component coupling that joins an a...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Panda, Santanu, Ready, Joseph M.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5572568/
https://ncbi.nlm.nih.gov/pubmed/28414430
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b01410
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